Waste-free electrochemical oxidation of alcohols in water

Giovanni Palmisano, Giovanni Palmisano, Rosaria Ciriminna, Mario Pagliaro

Risultato della ricerca: Articlepeer review

43 Citazioni (Scopus)


We describe a new sol-gel molecular electrode made of a thin layer of organosilica doped with the nitroxyl radical TEMPO (2,2,6,6-tetrame-thylpiperidine-1-oxyl) electrodeposited on the surface of an ITO-coated glass and its employment as a selective and versatile oxidation catalyst in the electrochemical conversion of different alcohols to carbonyl compounds. Environmentally friendly water or a water/acetonitrile mixture buffered with bicarbonate is used as solvent. The electrode is highly stable and it can be reused for a prolonged period of time allowing easy separation from the products.
Lingua originaleEnglish
pagine (da-a)2033-2037
Numero di pagine5
Stato di pubblicazionePublished - 2006

All Science Journal Classification (ASJC) codes

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  • ???subjectarea.asjc.1600.1605???


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