Waste-free electrochemical oxidation of alcohols in water

Giovanni Palmisano, Giovanni Palmisano, Rosaria Ciriminna, Mario Pagliaro

Risultato della ricerca: Article

29 Citazioni (Scopus)

Abstract

We describe a new sol-gel molecular electrode made of a thin layer of organosilica doped with the nitroxyl radical TEMPO (2,2,6,6-tetrame-thylpiperidine-1-oxyl) electrodeposited on the surface of an ITO-coated glass and its employment as a selective and versatile oxidation catalyst in the electrochemical conversion of different alcohols to carbonyl compounds. Environmentally friendly water or a water/acetonitrile mixture buffered with bicarbonate is used as solvent. The electrode is highly stable and it can be reused for a prolonged period of time allowing easy separation from the products.
Lingua originaleEnglish
pagine (da-a)2033-2037
Numero di pagine5
RivistaADVANCED SYNTHESIS & CATALYSIS
Volume348
Stato di pubblicazionePublished - 2006

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All Science Journal Classification (ASJC) codes

  • Catalysis
  • Organic Chemistry

Cita questo

Palmisano, G., Palmisano, G., Ciriminna, R., & Pagliaro, M. (2006). Waste-free electrochemical oxidation of alcohols in water. ADVANCED SYNTHESIS & CATALYSIS, 348, 2033-2037.