Utilization of Impedance Spectroscopy to investigate the self-assembly behavior of amphiphiles soluble in supercritical carbon dioxide: preliminary results

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Abstract

A mixture of CO2, water, methyl orange (MO) and Dynol 604 surfactant was analyzed at 309K and 20MPa simultaneously by impedance andUV–vis spectroscopy. A plot of the static dielectric constant as a function of the surfactant concentration was obtained using a suitable equivalentcircuit to elaborate impedance data. Experimental points can be fitted by two different straight lines whose intersection occurs at about 0.13%(w/w) concentration of Dynol. When the surfactant concentration crossed the aforementioned value, a peak was detectable in the UV–vis spectrumat a wavelength range corresponding to the absorption of MO; absorbance of the peak increased with the surfactant concentration. As it has beenalready shown that Dynol 604 stabilizes microemulsions of water in CO2, these preliminary results suggest that measurements of dielectric constantcan be used to detect micellization of amphiphiles soluble in supercritical CO2.
Lingua originaleEnglish
pagine (da-a)183-188
RivistaTHE JOURNAL OF SUPERCRITICAL FLUIDS
Volume40
Stato di pubblicazionePublished - 2007

All Science Journal Classification (ASJC) codes

  • ???subjectarea.asjc.1500.1500???
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry

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