Triggering Dissymmetry in Achiral Dye Molecules by Chiral Solvents:Circular Dichroism Experiments and DFT Calculations

Vincenzo Turco Liveri, Marco Passarello, Sergio Abbate, Giovanna Longhi, France Lebon, Marco Passarello

Risultato della ricerca: Articlepeer review

7 Citazioni (Scopus)

Abstract

The electronic circular dichroism spectra of achiral product ‘‘Lumogen F Red’’(ROT-300) in four different chiral solvents are recorded at different temperatures. DFT calculationsallow to identify two enantiomeric conformers for ROT-300. In vacuo they are equallypopulated; in chiral solvents one enantiomer prevails. Thermodynamic quantities involved inthe chiral preference are derived.
Lingua originaleEnglish
pagine (da-a)950-955
Numero di pagine6
RivistaChirality
Volume23
Stato di pubblicazionePublished - 2011

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry
  • Catalysis
  • Pharmacology
  • Drug Discovery
  • Spectroscopy
  • Organic Chemistry

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