The formal redox potential of the Ti(IV, III) couple at 25°C in 1 M HCl 2 M NaCl medium

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Abstract

The formal redox potential of the Ti(IV, III) couple has been determined at 25 °C in 1 M HCl, 2 M NaCl aqueous medium, by emf measurements of a junction-free cell with glass and mercury electrodes. Ti(III) and Ti(IV) concentrations were changed by controlled electrolysis. The mean value of the searched formal potential, in a large range of total titanium concentration, is 9 ± 1 mV against the molar hydrogen electrode in the same ionic medium.
Lingua originaleEnglish
pagine (da-a)713-721
Numero di pagine9
RivistaAnnali di Chimica
Volume97
Stato di pubblicazionePublished - 2007

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry
  • ???subjectarea.asjc.2300.2300???

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