SYNTHESIS OF CYANOACETIC ACID BY CARBON DIOXIDE AND ELECTROGENERATED ACETONITRILE ANION IN UNDIVIDED CELLS EQUIPPED WITH SACRIFICIAL ANODES

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Abstract

The electrochemical synthesis of cyanoacetic acid was performed by cathodic reduction of tetraalkylammonium salts (R4NX) in acetonitrile in undivided cells equipped with sacrificial anodes with concomitant or subsequent addition of carbon dioxide. These syntheses avoid the use of dangerous reagents, yield cyanoacetic acid in moderate faradic yields and confirm that the cathodic reduction of tetraalkylammonium salts in the presence of acetonitrile leads to the formation of the anion CNCH2-.
Lingua originaleEnglish
pagine (da-a)175-178
RivistaJournal of Electroanalytical Chemistry
Volume614
Stato di pubblicazionePublished - 2008

All Science Journal Classification (ASJC) codes

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  • ???subjectarea.asjc.1500.1500???
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