Synthesis of copper(II) complexes of new carbon-scorpionate ligands

Arturo Silvestri; Giampaolo Barone; Giuseppe Ruisi; Gianfranco Fontana; Michele Abbate

Synthesis of copper(II) complexes of new carbon-scorpionate ligands

Arturo Silvestri, Giampaolo Barone, Giuseppe Ruisi, Gianfranco Fontana, Michele Abbate

Scienze e Tecnologie Biologiche Chimiche e Farmaceutiche

Risultato della ricerca: Other

Abstract

A set of new “carbon-based” scorpionate ligands based on S- and N-containing heterocyclic moieties have been synthesized. They offer the advantage of a higher stability with respect to the “classical” boron-based scorpionate ligands and also a certain degree of hydrophilicity. The synthesis of these ligands was accomplished by the coupling reaction of the N-methylimidazolyllithium with a suitable electrophilic partner. The reaction yield ranges from 40% to 65%. Preliminary results on the synthesis and characterization of the related copper(II) complex are also presented.

Lingua originale	English
Numero di pagine	12
Stato di pubblicazione	Published - 2009

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title = "Synthesis of copper(II) complexes of new carbon-scorpionate ligands",

abstract = "A set of new “carbon-based” scorpionate ligands based on S- and N-containing heterocyclic moieties have been synthesized. They offer the advantage of a higher stability with respect to the “classical” boron-based scorpionate ligands and also a certain degree of hydrophilicity. The synthesis of these ligands was accomplished by the coupling reaction of the N-methylimidazolyllithium with a suitable electrophilic partner. The reaction yield ranges from 40% to 65%. Preliminary results on the synthesis and characterization of the related copper(II) complex are also presented.",

keywords = "carbon-scorpionate, copper, carbon-scorpionate, copper",

author = "Arturo Silvestri and Giampaolo Barone and Giuseppe Ruisi and Gianfranco Fontana and Michele Abbate",

year = "2009",

language = "English",

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TY - CONF

T1 - Synthesis of copper(II) complexes of new carbon-scorpionate ligands

AU - Silvestri, Arturo

AU - Barone, Giampaolo

AU - Ruisi, Giuseppe

AU - Fontana, Gianfranco

AU - Abbate, Michele

PY - 2009

Y1 - 2009

N2 - A set of new “carbon-based” scorpionate ligands based on S- and N-containing heterocyclic moieties have been synthesized. They offer the advantage of a higher stability with respect to the “classical” boron-based scorpionate ligands and also a certain degree of hydrophilicity. The synthesis of these ligands was accomplished by the coupling reaction of the N-methylimidazolyllithium with a suitable electrophilic partner. The reaction yield ranges from 40% to 65%. Preliminary results on the synthesis and characterization of the related copper(II) complex are also presented.

AB - A set of new “carbon-based” scorpionate ligands based on S- and N-containing heterocyclic moieties have been synthesized. They offer the advantage of a higher stability with respect to the “classical” boron-based scorpionate ligands and also a certain degree of hydrophilicity. The synthesis of these ligands was accomplished by the coupling reaction of the N-methylimidazolyllithium with a suitable electrophilic partner. The reaction yield ranges from 40% to 65%. Preliminary results on the synthesis and characterization of the related copper(II) complex are also presented.

KW - carbon-scorpionate

KW - copper

KW - carbon-scorpionate

KW - copper

UR - http://hdl.handle.net/10447/56666

M3 - Other

ER -