Synthesis of Amino-1,2,4-triazoles by Reductive ANRORC Rearrangements of 1,2,4-Oxadiazoles.

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The reaction of various 1,2,4-oxadiazoles with an excessof hydrazine in DMF has been investigated. 3-Amino-1,2,4-triazoles are produced through a reductive ANRORCpathway consisting of the addition of hydrazine to the1,2,4-oxadiazole followed by ring-opening, ring-closure,and final reduction of the 3-hydroxylamino-1,2,4-triazoleintermediate. The general applicability of 1,2,4-oxadiazolesANRORC reactivity is demonstrated also in theabsence of C(5)-linked electron-withdrawing groups.
Lingua originaleEnglish
pagine (da-a)8724-
Numero di pagine4
RivistaJournal of Organic Chemistry
Stato di pubblicazionePublished - 2010

All Science Journal Classification (ASJC) codes

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