Synthesis and crystal structure of [(PhenH)(PhenH2)][BiCl6] . 2H2O with different o-phenanthroline protonations.

Giuseppe Alonzo, Girolamo Casella, Franco Benetollo, Gabriella Bombieri, Nuccio Bertazzi

Risultato della ricerca: Articlepeer review

6 Citazioni (Scopus)

Abstract

The reaction between bismuthate oxide and phen (1,10-phenanthroline) in acid medium led to the isolation of the unusual [(PhenH)(PhenH2)][BiCl6] 2H2O derivative, which has beencharacterized by X-ray analysis and IR spectroscopy. The compound crystallizes in the triclinic space group P1 with a = 8.313(2), b = 9.349(2), c = 9.807(3) A, a = 86.39(3), B = 110.27(3)and y = 106.48(3)°. The crystal structure is made of [BiCl6] 3- anions and [(PhenHXPhenr2)]3+cations. A network of hydrogen bond interactions involving the two clathrated water molecules,the phenanthroline moiety and the chlorines characterizes the entire structure.
Lingua originaleEnglish
pagine (da-a)791-796
Numero di pagine6
RivistaJournal of Chemical Crystallography
Volume28
Stato di pubblicazionePublished - 1998

All Science Journal Classification (ASJC) codes

  • ???subjectarea.asjc.1600.1600???
  • Condensed Matter Physics

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