Surface characterization of metal ions loaded TiO2 photocatalysts: structure-activity relationship

Giuseppe Marci', Agatino Di Paola, Leonardo Palmisano, Elisa Isabel Garcia Lopez, Anna Maria Venezia, Vicente Rives, Cristina Martín

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85 Citazioni (Scopus)

Abstract

Transition metal loaded TiO2 powders were characterised and tested for the photodegradation of some organic acids. Both Lewis and Brønsted surface acid sites were present in the samples containing large amounts of Mo, V and W. The Brønsted sites are associated to the presence of the transition metals as they do not exist in the unloaded support, and in particular to the presence of these metals in high oxidation states. The trend of the pzc values of the various powders matches rather well both with the surface acidity of the samples experimentally determined by NH3 adsorption and with a scale of acidity/basicity for bulk binary oxides. XPS investigation indicates that only the presence of Cu(II) is able to modify the TiO2 valence band spectrum. The photodegradation results have confirmed that the presence of transition metal ions generally reduces the photocatalytic activity of TiO2. Surface acidity addresses the reactivity for the degradation of methanoic and benzoic acid: the more basic the surface of the powders the higher the rate of substrate disappearance. No relation with the acidity has been found in the case of ethanoic acid.
Lingua originaleEnglish
pagine (da-a)223-233
Numero di pagine11
RivistaAPPLIED CATALYSIS. B, ENVIRONMENTAL
Volume48
Stato di pubblicazionePublished - 2004

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Photocatalysts
Acidity
Metal ions
acidity
transition element
Powders
Transition metals
ion
metal
Photodegradation
photodegradation
acid
Benzoic Acid
Benzoic acid
Organic acids
Alkalinity
Valence bands
organic acid
Acetic acid
Oxides

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Environmental Science(all)
  • Process Chemistry and Technology

Cita questo

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title = "Surface characterization of metal ions loaded TiO2 photocatalysts: structure-activity relationship",
abstract = "Transition metal loaded TiO2 powders were characterised and tested for the photodegradation of some organic acids. Both Lewis and Br{\o}nsted surface acid sites were present in the samples containing large amounts of Mo, V and W. The Br{\o}nsted sites are associated to the presence of the transition metals as they do not exist in the unloaded support, and in particular to the presence of these metals in high oxidation states. The trend of the pzc values of the various powders matches rather well both with the surface acidity of the samples experimentally determined by NH3 adsorption and with a scale of acidity/basicity for bulk binary oxides. XPS investigation indicates that only the presence of Cu(II) is able to modify the TiO2 valence band spectrum. The photodegradation results have confirmed that the presence of transition metal ions generally reduces the photocatalytic activity of TiO2. Surface acidity addresses the reactivity for the degradation of methanoic and benzoic acid: the more basic the surface of the powders the higher the rate of substrate disappearance. No relation with the acidity has been found in the case of ethanoic acid.",
author = "Giuseppe Marci' and {Di Paola}, Agatino and Leonardo Palmisano and {Garcia Lopez}, {Elisa Isabel} and Venezia, {Anna Maria} and Vicente Rives and Cristina Mart{\'i}n",
year = "2004",
language = "English",
volume = "48",
pages = "223--233",
journal = "Applied Catalysis B: Environmental",
issn = "0926-3373",
publisher = "Elsevier",

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TY - JOUR

T1 - Surface characterization of metal ions loaded TiO2 photocatalysts: structure-activity relationship

AU - Marci', Giuseppe

AU - Di Paola, Agatino

AU - Palmisano, Leonardo

AU - Garcia Lopez, Elisa Isabel

AU - Venezia, Anna Maria

AU - Rives, Vicente

AU - Martín, Cristina

PY - 2004

Y1 - 2004

N2 - Transition metal loaded TiO2 powders were characterised and tested for the photodegradation of some organic acids. Both Lewis and Brønsted surface acid sites were present in the samples containing large amounts of Mo, V and W. The Brønsted sites are associated to the presence of the transition metals as they do not exist in the unloaded support, and in particular to the presence of these metals in high oxidation states. The trend of the pzc values of the various powders matches rather well both with the surface acidity of the samples experimentally determined by NH3 adsorption and with a scale of acidity/basicity for bulk binary oxides. XPS investigation indicates that only the presence of Cu(II) is able to modify the TiO2 valence band spectrum. The photodegradation results have confirmed that the presence of transition metal ions generally reduces the photocatalytic activity of TiO2. Surface acidity addresses the reactivity for the degradation of methanoic and benzoic acid: the more basic the surface of the powders the higher the rate of substrate disappearance. No relation with the acidity has been found in the case of ethanoic acid.

AB - Transition metal loaded TiO2 powders were characterised and tested for the photodegradation of some organic acids. Both Lewis and Brønsted surface acid sites were present in the samples containing large amounts of Mo, V and W. The Brønsted sites are associated to the presence of the transition metals as they do not exist in the unloaded support, and in particular to the presence of these metals in high oxidation states. The trend of the pzc values of the various powders matches rather well both with the surface acidity of the samples experimentally determined by NH3 adsorption and with a scale of acidity/basicity for bulk binary oxides. XPS investigation indicates that only the presence of Cu(II) is able to modify the TiO2 valence band spectrum. The photodegradation results have confirmed that the presence of transition metal ions generally reduces the photocatalytic activity of TiO2. Surface acidity addresses the reactivity for the degradation of methanoic and benzoic acid: the more basic the surface of the powders the higher the rate of substrate disappearance. No relation with the acidity has been found in the case of ethanoic acid.

UR - http://hdl.handle.net/10447/2629

M3 - Article

VL - 48

SP - 223

EP - 233

JO - Applied Catalysis B: Environmental

JF - Applied Catalysis B: Environmental

SN - 0926-3373

ER -