Structure–property relationships in bionanocomposites for pipe extrusion applications

Luigi Botta, Francesco Paolo La Mantia, Maria Chiara Mistretta, Maria Chiara Mistretta, Rossella Arrigo, Francesco Paolo La Mantia, Antonino Oliveri, Giulio Malucelli, Luigi Botta

Risultato della ricerca: Articlepeer review

3 Citazioni (Scopus)

Abstract

In this work, bionanocomposites based on different biodegradable polymers and two types of nanofillers, namely a nanosized calcium carbonate and an organomodified nanoclay, were produced through melt extrusion, with the aim to evaluate the possible applications of these materials as a potential alternative to traditional fossil fuel‐derived polyolefins, for the production of irrigation pipes. The rheological behavior of the formulated systems was thoroughly evaluated by exploiting different flow regimes, and the obtained results indicated a remarkable effect of the in-troduced nanofillers on the low‐frequency rheological response, especially in nanoclay‐based bi-onanocomposites. Conversely, the shear viscosity at a high shear rate was almost unaffected by the presence of both types of nanofillers, as well as the rheological response under nonisothermal elon-gational flow. In addition, the analysis of the mechanical properties of the formulated materials indicated that the embedded nanofillers increased the elastic modulus when compared to the unfilled counterparts, notwithstanding a slight decrease of the material ductility. Finally, the processing behavior of unfilled biopolymers and bionanocomposites was evaluated, allowing for se-lecting the most suitable material and thus fulfilling the processability requirements for pipe extrusion applications.
Lingua originaleEnglish
pagine (da-a)1-13
Numero di pagine13
RivistaPolymers
Volume13
Stato di pubblicazionePublished - 2021

All Science Journal Classification (ASJC) codes

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  • ???subjectarea.asjc.2500.2507???

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