Structure of the FeBTC Metal–Organic Framework: A Model Based on the Local Environment Study

Risultato della ricerca: Articlepeer review

32 Citazioni (Scopus)

Abstract

The local environment of iron in FeBTC, a metal organic framework commercially known as Basolite F300, is investigated combining XANES and EXAFS studies of the iron K-edge. The building block of the FeBTC can be described as an iron acetate moiety. Dehydration induces a change in the coordination of the first shell while preserving the network. We propose that the local structure around Fe atoms does not undergo a rearrangement, thus, leading to the formation of an open site. The analysis conveys that the FeBTC is a disordered network of locally ordered blocks.
Lingua originaleEnglish
pagine (da-a)7826-7830
Numero di pagine5
RivistaJOURNAL OF PHYSICAL CHEMISTRY. C
Volume119
Stato di pubblicazionePublished - 2015

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • ???subjectarea.asjc.2100.2100???
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

Fingerprint Entra nei temi di ricerca di 'Structure of the FeBTC Metal–Organic Framework: A Model Based on the Local Environment Study'. Insieme formano una fingerprint unica.

Cita questo