Structure of D-ribonic acid-dimethyltin(IV) in coordinating solvents: an experimental and DFT 119Sn NMR study.

Girolamo Casella, Lorenzo Pellerito, Giacomo Saielli, Alessandro Bagno, Ivan Diego Sciacca, Nuccio Bertazzi

Risultato della ricerca: Articlepeer review

8 Citazioni (Scopus)

Abstract

We have investigated a newly synthesized complex of D-ribonic acid with dimethyltin(IV). The structure of the complex in solution has been characterized by means of 1H, 13C, and 119Sn NMR and by DFT calculations. The comparison of experimental and computational results allowed the determination of the stable conformation in solution as well as the detection of a dimerization process. Moreover, evidence is given of active coordination of the metal by the solvent.
Lingua originaleEnglish
pagine (da-a)874-883
Numero di pagine10
RivistaJournal of Physical Organic Chemistry
Volume19
Stato di pubblicazionePublished - 2006

All Science Journal Classification (ASJC) codes

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