Structural insight on organosilica electrodes for waste-free alcohol oxidations

Giovanni Palmisano, Giovanni Palmisano, Rosaria Ciriminna, Mario Pagliaro, Daniel Mandler

Risultato della ricerca: Article

5 Citazioni (Scopus)

Abstract

Organic modification of sol-gel catalytic glassy electrodes made of a thin layer of organosilica doped with nitroxyl radical TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy) crucially enhances stability in the waste-free oxidation of alcohols to carbonyls in water. Structural comparison between analogous films made of organosilica and unmodified SiO2 shows that the origin of the pronounced stable activity of the ORMOSIL film lies in high hydrophobic and also in the pronounced low degree of hydrophilicity.
Lingua originaleEnglish
pagine (da-a)55-58
Numero di pagine4
RivistaCatalysis Letters
Volume114
Stato di pubblicazionePublished - 2007

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All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cita questo

Palmisano, G., Palmisano, G., Ciriminna, R., Pagliaro, M., & Mandler, D. (2007). Structural insight on organosilica electrodes for waste-free alcohol oxidations. Catalysis Letters, 114, 55-58.