Structural insight on organosilica electrodes for waste-free alcohol oxidations

Giovanni Palmisano; Giovanni Palmisano; Rosaria Ciriminna; Mario Pagliaro; Daniel Mandler

Structural insight on organosilica electrodes for waste-free alcohol oxidations

Giovanni Palmisano, Giovanni Palmisano, Rosaria Ciriminna, Mario Pagliaro, Daniel Mandler

Fisica e Chimica - Emilio Segrè

Risultato della ricerca: Article › peer review

7 Citazioni (Scopus)

Abstract

Organic modification of sol-gel catalytic glassy electrodes made of a thin layer of organosilica doped with nitroxyl radical TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy) crucially enhances stability in the waste-free oxidation of alcohols to carbonyls in water. Structural comparison between analogous films made of organosilica and unmodified SiO2 shows that the origin of the pronounced stable activity of the ORMOSIL film lies in high hydrophobic and also in the pronounced low degree of hydrophilicity.

Lingua originale	English
pagine (da-a)	55-58
Numero di pagine	4
Rivista	Catalysis Letters
Volume	114
Stato di pubblicazione	Published - 2007

All Science Journal Classification (ASJC) codes

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???subjectarea.asjc.1600.1600???

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title = "Structural insight on organosilica electrodes for waste-free alcohol oxidations",

abstract = "Organic modification of sol-gel catalytic glassy electrodes made of a thin layer of organosilica doped with nitroxyl radical TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy) crucially enhances stability in the waste-free oxidation of alcohols to carbonyls in water. Structural comparison between analogous films made of organosilica and unmodified SiO2 shows that the origin of the pronounced stable activity of the ORMOSIL film lies in high hydrophobic and also in the pronounced low degree of hydrophilicity.",

keywords = "TEMPO, alcohols, anodic, green chemistry, oxidation, sol-gel, TEMPO, alcohols, anodic, green chemistry, oxidation, sol-gel",

author = "Giovanni Palmisano and Giovanni Palmisano and Rosaria Ciriminna and Mario Pagliaro and Daniel Mandler",

year = "2007",

language = "English",

volume = "114",

pages = "55--58",

journal = "Catalysis Letters",

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TY - JOUR

T1 - Structural insight on organosilica electrodes for waste-free alcohol oxidations

AU - Palmisano, Giovanni

AU - Ciriminna, Rosaria

AU - Pagliaro, Mario

AU - Mandler, Daniel

PY - 2007

Y1 - 2007

N2 - Organic modification of sol-gel catalytic glassy electrodes made of a thin layer of organosilica doped with nitroxyl radical TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy) crucially enhances stability in the waste-free oxidation of alcohols to carbonyls in water. Structural comparison between analogous films made of organosilica and unmodified SiO2 shows that the origin of the pronounced stable activity of the ORMOSIL film lies in high hydrophobic and also in the pronounced low degree of hydrophilicity.

AB - Organic modification of sol-gel catalytic glassy electrodes made of a thin layer of organosilica doped with nitroxyl radical TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy) crucially enhances stability in the waste-free oxidation of alcohols to carbonyls in water. Structural comparison between analogous films made of organosilica and unmodified SiO2 shows that the origin of the pronounced stable activity of the ORMOSIL film lies in high hydrophobic and also in the pronounced low degree of hydrophilicity.

KW - TEMPO

KW - alcohols

KW - anodic

KW - green chemistry

KW - oxidation

KW - sol-gel

KW - TEMPO

KW - alcohols

KW - anodic

KW - green chemistry

KW - oxidation

KW - sol-gel

UR - http://hdl.handle.net/10447/18531

M3 - Article

SN - 1011-372X

VL - 114

SP - 55

EP - 58

JO - Catalysis Letters

JF - Catalysis Letters

ER -

Structural insight on organosilica electrodes for waste-free alcohol oxidations

Abstract

All Science Journal Classification (ASJC) codes

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