Solid State Analysis of Metal-Containing Polymers Employing Mossbauer Spectroscopy, Solid State NMR and F EI TOF MALDI MS

Lorenzo Pellerito, Tiziana Fiore, Claudia Pellerito, Michelangelo Scopelliti, Michael R. Roner, Frank D. Blum, Charles E. Carraher Jr., Girish Barot, Amitabh Battin, Manikantan B. Nair, Anna Zhao

Risultato della ricerca: Article

11 Citazioni (Scopus)

Abstract

Polymers in general and metal-containing polymers in particular are often sparingly soluble or insoluble, in contrast to small molecules. Thus, special significance is attached to characterization techniques that can be applied to the materials as solids. Here, three techniques are discussed that give structural information gained from the solid material. Mossbauer spectroscopy is a powerful technique that may give information on the structure about the metal-containing moiety for about 44 different nuclei. Its use in describing the structure of the product obtained from organotin dichlorides and the unsymmetrical ciprofloxacin is presented along with the reaction implications of the results. Solid state NMR is also a useful tool in describing the structure of metal-containing polymers and its use is briefly described. Finally, MALDI MS can be used to gain structural information. For many metals it is particularly useful because of the presence of different isotopes that allow the identification of units through comparison of these isotope abundances with ion fragment clusters. Each of these tools can provide important structural characterization information.
Lingua originaleEnglish
pagine (da-a)570-585
Numero di pagine16
RivistaJournal of Inorganic and Organometallic Polymers and Materials
Volume20
Stato di pubblicazionePublished - 2010

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Mossbauer spectroscopy
Polymers
Metals
Nuclear magnetic resonance
Isotopes
Ciprofloxacin
Ions
Molecules

All Science Journal Classification (ASJC) codes

  • Polymers and Plastics
  • Materials Chemistry

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Solid State Analysis of Metal-Containing Polymers Employing Mossbauer Spectroscopy, Solid State NMR and F EI TOF MALDI MS. / Pellerito, Lorenzo; Fiore, Tiziana; Pellerito, Claudia; Scopelliti, Michelangelo; Roner, Michael R.; Blum, Frank D.; Carraher Jr., Charles E.; Barot, Girish; Battin, Amitabh; Nair, Manikantan B.; Zhao, Anna.

In: Journal of Inorganic and Organometallic Polymers and Materials, Vol. 20, 2010, pag. 570-585.

Risultato della ricerca: Article

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AU - Pellerito, Lorenzo

AU - Fiore, Tiziana

AU - Pellerito, Claudia

AU - Scopelliti, Michelangelo

AU - Roner, Michael R.

AU - Blum, Frank D.

AU - Carraher Jr., Charles E.

AU - Barot, Girish

AU - Battin, Amitabh

AU - Nair, Manikantan B.

AU - Zhao, Anna

PY - 2010

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N2 - Polymers in general and metal-containing polymers in particular are often sparingly soluble or insoluble, in contrast to small molecules. Thus, special significance is attached to characterization techniques that can be applied to the materials as solids. Here, three techniques are discussed that give structural information gained from the solid material. Mossbauer spectroscopy is a powerful technique that may give information on the structure about the metal-containing moiety for about 44 different nuclei. Its use in describing the structure of the product obtained from organotin dichlorides and the unsymmetrical ciprofloxacin is presented along with the reaction implications of the results. Solid state NMR is also a useful tool in describing the structure of metal-containing polymers and its use is briefly described. Finally, MALDI MS can be used to gain structural information. For many metals it is particularly useful because of the presence of different isotopes that allow the identification of units through comparison of these isotope abundances with ion fragment clusters. Each of these tools can provide important structural characterization information.

AB - Polymers in general and metal-containing polymers in particular are often sparingly soluble or insoluble, in contrast to small molecules. Thus, special significance is attached to characterization techniques that can be applied to the materials as solids. Here, three techniques are discussed that give structural information gained from the solid material. Mossbauer spectroscopy is a powerful technique that may give information on the structure about the metal-containing moiety for about 44 different nuclei. Its use in describing the structure of the product obtained from organotin dichlorides and the unsymmetrical ciprofloxacin is presented along with the reaction implications of the results. Solid state NMR is also a useful tool in describing the structure of metal-containing polymers and its use is briefly described. Finally, MALDI MS can be used to gain structural information. For many metals it is particularly useful because of the presence of different isotopes that allow the identification of units through comparison of these isotope abundances with ion fragment clusters. Each of these tools can provide important structural characterization information.

UR - http://hdl.handle.net/10447/52677

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JO - Journal of Inorganic and Organometallic Polymers and Materials

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