Regioselective Epoxide Ring Opening. Steroselective Synthesis of a Tetrahydropyran Ring

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Abstract

The stereoselective synthesis of a 2-substituted tetrahydropyran with adjacent alkoxy-bearing stereogenic centre is described. The key steps of this synthesis were the stereoselective epoxidation of an allylic alcohol and the regioselective epoxide ring opening by lithium aluminum hydride. The regio and stereoselective synthesis of a trihydroxyselenide and a trihydroxysulfide is also described. The latter compounds are not suitable for cyclization to tetrahydrofuran ring.
Lingua originaleEnglish
pagine (da-a)865-869
Numero di pagine5
RivistaJOURNAL OF HETEROCYCLIC CHEMISTRY
Volume35
Stato di pubblicazionePublished - 1998

All Science Journal Classification (ASJC) codes

  • ???subjectarea.asjc.1600.1605???

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