Redox materials by covalent entrapment of redox-active dirhodium(II,II) species in a siloxane network

Bruno Giuseppe Pignataro; Giuseppe Tresoldi; Bruno Pignataro; Claudia Forte; Sandra Lo Schiavo; Pasquale Piraino

Redox materials by covalent entrapment of redox-active dirhodium(II,II) species in a siloxane network

Bruno Giuseppe Pignataro, Giuseppe Tresoldi, Bruno Pignataro, Claudia Forte, Sandra Lo Schiavo, Pasquale Piraino

Fisica e Chimica - Emilio Segrè

Risultato della ricerca: Article › peer review

4 Citazioni (Scopus)

Abstract

Hydrolysis and polycondensation of the coupling agent (aminopropyl) triethoxysilane (APS), axially coordinated to the redox-active complex [Rh 2(form)2(CH3COO)2-(APS) 2], lead to the insertion of redox-active inorganic microdomains into a siloxane network; the new polymers undergo cyclic redox reactions indicating that dirhodium(II,II) centres retain their redox activity even when incorporated into siloxane networks.

Lingua originale	English
pagine (da-a)	1033-1037
Numero di pagine	5
Rivista	Macromolecular Rapid Communications
Volume	25
Stato di pubblicazione	Published - 2004

All Science Journal Classification (ASJC) codes

Organic Chemistry
Polymers and Plastics
Materials Chemistry

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title = "Redox materials by covalent entrapment of redox-active dirhodium(II,II) species in a siloxane network",

abstract = "Hydrolysis and polycondensation of the coupling agent (aminopropyl) triethoxysilane (APS), axially coordinated to the redox-active complex [Rh 2(form)2(CH3COO)2-(APS) 2], lead to the insertion of redox-active inorganic microdomains into a siloxane network; the new polymers undergo cyclic redox reactions indicating that dirhodium(II,II) centres retain their redox activity even when incorporated into siloxane networks.",

author = "Pignataro, {Bruno Giuseppe} and Giuseppe Tresoldi and Bruno Pignataro and Claudia Forte and {Lo Schiavo}, Sandra and Pasquale Piraino",

year = "2004",

language = "English",

volume = "25",

pages = "1033--1037",

journal = "Macromolecular Rapid Communications",

issn = "1022-1336",

publisher = "Wiley-VCH Verlag",

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TY - JOUR

T1 - Redox materials by covalent entrapment of redox-active dirhodium(II,II) species in a siloxane network

AU - Pignataro, Bruno Giuseppe

AU - Tresoldi, Giuseppe

AU - Pignataro, Bruno

AU - Forte, Claudia

AU - Lo Schiavo, Sandra

AU - Piraino, Pasquale

PY - 2004

Y1 - 2004

N2 - Hydrolysis and polycondensation of the coupling agent (aminopropyl) triethoxysilane (APS), axially coordinated to the redox-active complex [Rh 2(form)2(CH3COO)2-(APS) 2], lead to the insertion of redox-active inorganic microdomains into a siloxane network; the new polymers undergo cyclic redox reactions indicating that dirhodium(II,II) centres retain their redox activity even when incorporated into siloxane networks.

AB - Hydrolysis and polycondensation of the coupling agent (aminopropyl) triethoxysilane (APS), axially coordinated to the redox-active complex [Rh 2(form)2(CH3COO)2-(APS) 2], lead to the insertion of redox-active inorganic microdomains into a siloxane network; the new polymers undergo cyclic redox reactions indicating that dirhodium(II,II) centres retain their redox activity even when incorporated into siloxane networks.

UR - http://hdl.handle.net/10447/22974

UR - https://onlinelibrary.wiley.com/doi/full/10.1002/marc.200400033

M3 - Article

VL - 25

SP - 1033

EP - 1037

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

SN - 1022-1336

ER -