Redox materials by covalent entrapment of redox-active dirhodium(II,II) species in a siloxane network

Bruno Giuseppe Pignataro, Giuseppe Tresoldi, Bruno Pignataro, Claudia Forte, Sandra Lo Schiavo, Pasquale Piraino

Risultato della ricerca: Articlepeer review

4 Citazioni (Scopus)

Abstract

Hydrolysis and polycondensation of the coupling agent (aminopropyl) triethoxysilane (APS), axially coordinated to the redox-active complex [Rh 2(form)2(CH3COO)2-(APS) 2], lead to the insertion of redox-active inorganic microdomains into a siloxane network; the new polymers undergo cyclic redox reactions indicating that dirhodium(II,II) centres retain their redox activity even when incorporated into siloxane networks.
Lingua originaleEnglish
pagine (da-a)1033-1037
Numero di pagine5
RivistaMacromolecular Rapid Communications
Volume25
Stato di pubblicazionePublished - 2004

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry

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