Abstract
Hydrolysis and polycondensation of the coupling agent (aminopropyl) triethoxysilane (APS), axially coordinated to the redox-active complex [Rh 2(form)2(CH3COO)2-(APS) 2], lead to the insertion of redox-active inorganic microdomains into a siloxane network; the new polymers undergo cyclic redox reactions indicating that dirhodium(II,II) centres retain their redox activity even when incorporated into siloxane networks.
Lingua originale | English |
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pagine (da-a) | 1033-1037 |
Numero di pagine | 5 |
Rivista | Macromolecular Rapid Communications |
Volume | 25 |
Stato di pubblicazione | Published - 2004 |
All Science Journal Classification (ASJC) codes
- ???subjectarea.asjc.1600.1605???
- ???subjectarea.asjc.2500.2507???
- ???subjectarea.asjc.2500.2505???