Photocatalytic partial oxidation of limonene to 1,2 limonene oxide

Claudio De Pasquale, Leonardo Palmisano, Francesco Parrino, Rosaria Ciriminna, Mario Pagliaro

Risultato della ricerca: Articlepeer review

19 Citazioni (Scopus)

Abstract

The silylation of crystalline TiO2P25, commonly used for photocatalytic degradation of pollutants, results in an exceptionally selective catalyst for the aerobic limonene epoxidation to 1,2-limonene oxide under solar light irradiation. The hypothesized mechanism involves the singlet oxygen generated through energy transfer from the excited TiO2to adsorbed O2molecules. The reaction product is the valued precursor of bio-based poly(limonene carbonate), a thermoplastic polymer of superior thermal and optical properties whose industrial production is in need of an efficient green synthesis of limonene oxide.
Lingua originaleEnglish
pagine (da-a)1008-1011
Numero di pagine4
RivistaChemical Communications
Volume54
Stato di pubblicazionePublished - 2018

All Science Journal Classification (ASJC) codes

  • ???subjectarea.asjc.1500.1503???
  • ???subjectarea.asjc.2500.2504???
  • ???subjectarea.asjc.2500.2503???
  • ???subjectarea.asjc.1600.1600???
  • ???subjectarea.asjc.2500.2508???
  • ???subjectarea.asjc.2500.2506???
  • ???subjectarea.asjc.2500.2505???

Fingerprint

Entra nei temi di ricerca di 'Photocatalytic partial oxidation of limonene to 1,2 limonene oxide'. Insieme formano una fingerprint unica.

Cita questo