Oxadiazolyl-pyridinium as cationic scaffold for fluorinated ionic liquid crystals†

Ivana Pibiri, Antonio Palumbo Piccionello, Andrea Pace, Giuseppe Lazzara, Melina S. Weber, Melina S. Weber, Margit Schulze

Risultato della ricerca: Articlepeer review

Abstract

The synthesis and characterization of a new class of 1,2,4-oxadiazolylpyridinium as a cationic scaffold for fluorinated ionic liquid crystals is herein described. A series of 12 fluorinated heterocyclic salts based on a 1,2,4-oxadiazole moiety, connected through its C(5) or C(3) to an N-alkylpyridinium unit and a perfluoroheptyl chain, differing in the length of the alkyl chain and coun-terions, has been synthesized. As counterions iodide, bromide and bis(trifluoromethane)sulfonimide have been considered. The synthesis, structure, and liquid crystalline properties of these compounds are discussed on the basis of the tuned structural variables. The thermotropic properties of this series of salts have been investigated by differential scanning calorimetry and polarized optical microscopy. The results showed the existence of an enantiotropic mesomorphic smectic liquid crystalline phase for six bis(trifluoromethane)sulfonimide salts.
Lingua originaleEnglish
pagine (da-a)1-12
Numero di pagine12
RivistaAPPLIED SCIENCES
Volume11
Stato di pubblicazionePublished - 2021

All Science Journal Classification (ASJC) codes

  • ???subjectarea.asjc.2500.2500???
  • ???subjectarea.asjc.3100.3105???
  • ???subjectarea.asjc.2200.2200???
  • ???subjectarea.asjc.1500.1508???
  • ???subjectarea.asjc.1700.1706???
  • ???subjectarea.asjc.1500.1507???

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