On the photoreaction of some 1,2,4-oxadiazoles in the presence of 2,3-dimethyl-2-butene. Synthesis of N-imidoylaziridines

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Abstract

The photochemistry of some 3,5-disubstituted 1,2,4-oxadiazoles in the presence of 2,3-dimethyl-2-butene has been investigated. The irradiation in acetonitrile yielded differently substituted N-imidoyl-aziridines through an aziridination reaction involving an acyliminonitrene intermediate. Pyrolysis of N-imidoyl-aziridines produced the corresponding N-allylamidines through a ring opening process.
Lingua originaleEnglish
pagine (da-a)1529-1537
Numero di pagine9
RivistaHeterocycles
Volume71
Stato di pubblicazionePublished - 2007

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry
  • Pharmacology
  • Organic Chemistry

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