Local environment of Barium, Cerium and Yttrium in BaCe1-xYxO3-d ceramic protonic conductors

Antonino Martorana, Francesco Giannici, Deganello, Antonella Balerna, Arico, Alessandro Longo

Risultato della ricerca: Article

43 Citazioni (Scopus)

Abstract

Y-doped barium cerate protonic conductors with composition BaCe1 − xYxO3 − δ (x=0.02, 0.1, 0.2, 0.3) have been synthesized by sol–gel route,giving by X-ray diffraction tests a homogeneous crystalline phase. A commercial sample BaCe0.8Y0.2O3 − δ produced by combustion spray pyrolysiswas also provided for comparison aim. The local structure around the cations was studied by X-ray absorption spectroscopy at the K-edges of Ba, Ceand Y. It is demonstrated that the insertion of yttrium in the site of cerium produces a remarkable local distortion of the dopant first-shell octahedralenvironment that affects also the next coordination shells by a static disorder increasing with dopant amount. For a dopant concentration estimated asx N 0.17, a poorly crystallized yttrium oxide phase that cannot be detected by X-ray diffraction is segregated. The static disorder around Y noticeablyincreases in the protonated samples and can be related to a preferential location of protons near the dopant.
Lingua originaleEnglish
pagine (da-a)587-591
Numero di pagine5
RivistaSolid State Ionics
Volume178
Stato di pubblicazionePublished - 2007

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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