Lipase-catalysed preparation of acyl derivatives of the germacranolide sesquiterpenoid cnicin

Sergio Rosselli, Maurizio Bruno, Leandro N. Monsalve, Alicia Baldessari

Risultato della ricerca: Article

11 Citazioni (Scopus)

Abstract

Several acyl derivatives of cnicin were obtained through lipase-catalysed acylation and alcoholysis reactions.In most reactions lipases showed a regioselective behaviour affording only one product. Longerchain acyl derivatives were prepared at lower temperature than the used in lipase-catalysed reactions, topreclude side products formation. The enzymatic approach let to prepare a family of novel acetyl and fattyacid derivatives of cnicin which are not obtainable following traditional organic synthetic procedures.
Lingua originaleEnglish
pagine (da-a)40-47
Numero di pagine8
RivistaJOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC
Volume57
Stato di pubblicazionePublished - 2009

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Bioengineering
  • Biochemistry
  • Process Chemistry and Technology

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