Light-Activated Sensitive Probes for Amine Detection

Aurelio Bonasera, Virginia Valderrey, Aurelio Bonasera, Sebastian Fredrich, Stefan Hecht

Risultato della ricerca: Articlepeer review

37 Citazioni (Scopus)

Abstract

Our new, simple, and accurate colorimetric method is based on diarylethenes (DAEs) for the rapid detection of a wide range of primary and secondary amines. The probes consist of aldehyde- or ketone-substituted diarylethenes, which undergo an amine-induced decoloration reaction, selectively to give the ring-closed isomer. Thus, these probes can be activated at the desired moment by light irradiation, with a sensitivity that allows the detection of amines at concentrations as low as 10−6m in solution. In addition, the practical immobilization of DAEs on paper makes it possible to detect biogenic amines, such as cadaverine, in the gas phase above a threshold of 12 ppbv within 30 seconds.
Lingua originaleEnglish
pagine (da-a)1914-1918
Numero di pagine5
RivistaANGEWANDTE CHEMIE. INTERNATIONAL EDITION
Volume56
Stato di pubblicazionePublished - 2017

All Science Journal Classification (ASJC) codes

  • Catalysis
  • ???subjectarea.asjc.1600.1600???

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