TY - JOUR
T1 - In-situ monitoring by Raman spectroscopy of the thermal doping of graphene and MoS2 in O2-controlled atmosphere
AU - Gelardi, Franco Mario
AU - Agnello, Simonpietro
AU - Cannas, Marco
AU - Buscarino, Gianpiero
AU - Giannazzo, Filippo
AU - Magna, Antonino La
AU - Piazza, Aurora
AU - Fisichella, Gabriele
AU - Roccaforte, Fabrizio
PY - 2017
Y1 - 2017
N2 - The effects of temperature and atmosphere (air and O2) on the doping of monolayers of graphene (Gr) on SiO2 and Si substrates, and on the doping of MoS2 multilayer flakes transferred on the same substrates have been investigated. The investigations were carried out by in situ micro-Raman spectroscopy during thermal treatments up to 430 °C, and by atomic force microscopy (AFM). The spectral positions of the G and 2D Raman bands of Gr undergo only minor changes during treatment, while their amplitude and full width at half maximum (FWHM) vary as a function of the temperature and the used atmosphere. The thermal treatments in oxygen atmosphere show, in addition to a thermal effect, an effect attributable to a p-type doping through oxygen. The thermal broadening of the line shape, found during thermal treatments by in situ Raman measurements, can be related to thermal phonon effects. The absence of a band shift results from the balance between a red shift due to thermal effects and a blue shift induced by doping. This shows the potential of in situ measurements to follow the doping kinetics. The treatment of MoS2 in O2 has evidenced a progressive erosion of the flakes without relevant spectral changes in their central zone during in situ measurements. The formation of MoO3 on the edges of the flakes is observed indicative of the oxygen-activated transformation.
AB - The effects of temperature and atmosphere (air and O2) on the doping of monolayers of graphene (Gr) on SiO2 and Si substrates, and on the doping of MoS2 multilayer flakes transferred on the same substrates have been investigated. The investigations were carried out by in situ micro-Raman spectroscopy during thermal treatments up to 430 °C, and by atomic force microscopy (AFM). The spectral positions of the G and 2D Raman bands of Gr undergo only minor changes during treatment, while their amplitude and full width at half maximum (FWHM) vary as a function of the temperature and the used atmosphere. The thermal treatments in oxygen atmosphere show, in addition to a thermal effect, an effect attributable to a p-type doping through oxygen. The thermal broadening of the line shape, found during thermal treatments by in situ Raman measurements, can be related to thermal phonon effects. The absence of a band shift results from the balance between a red shift due to thermal effects and a blue shift induced by doping. This shows the potential of in situ measurements to follow the doping kinetics. The treatment of MoS2 in O2 has evidenced a progressive erosion of the flakes without relevant spectral changes in their central zone during in situ measurements. The formation of MoO3 on the edges of the flakes is observed indicative of the oxygen-activated transformation.
KW - 2
KW - Graphene
KW - MoS
KW - Raman spectroscopy
KW - Thermal doping
KW - Two-dimensional (2D) materials
KW - 2
KW - Graphene
KW - MoS
KW - Raman spectroscopy
KW - Thermal doping
KW - Two-dimensional (2D) materials
UR - http://hdl.handle.net/10447/225206
UR - http://www.beilstein-journals.org/bjnano/content/pdf/2190-4286-8-44.pdf
M3 - Article
VL - 8
SP - 418
EP - 424
JO - Beilstein Journal of Nanotechnology
JF - Beilstein Journal of Nanotechnology
SN - 2190-4286
ER -