Host-guest interactions involving cyclodextrins: useful complementary insights achieved by polarimetry

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29 Citazioni (Scopus)

Abstract

By means of simple polarimetry, we studied the binding abilities of native a-, b-, and g-cyclodextrins toward a group of suitably chosen model guests.We were able to get reliable estimations of the binding constants K, spread over a wide range (from 3.7 to 12,300 M1), allowing us to carry on interesting comparisons. A comprehensive discussion of polarimetric data, and in particular a detailed analysis of the variations DQ of molar optical activities consequent to inclusion, offered us the opportunity to get useful insights into the structure and dynamic behavior of host–guest complexes.
Lingua originaleEnglish
pagine (da-a)9163-9171
Numero di pagine9
RivistaTetrahedron
Volume63
Stato di pubblicazionePublished - 2007

All Science Journal Classification (ASJC) codes

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  • ???subjectarea.asjc.3000.3002???
  • ???subjectarea.asjc.1600.1605???

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