Heterogeneous versus Homogeneous Palladium Catalysts for Cross-Coupling Reactions

Piera Demma Cara', Valerica Pandarus, Piera Demmacarà, François Béland, Rosaria Ciriminna, Mario Pagliaro

Risultato della ricerca: Articlepeer review

204 Citazioni (Scopus)

Abstract

A large number of immobilized-Pd-catalysts for cross-coupling reactions have been introduced in the last decade. Are the observed catalyzed reactions truly heterogeneous or are they homogeneous due to leached palladium? This account critically addresses the leaching issue by selectively referring to some of the newly developed catalytic systems in an attempt to evaluate said systems based on uniform criteria. The report is concluded by identifying the relevant chemical and structural challenges in the field.
Lingua originaleEnglish
pagine (da-a)432-445
Numero di pagine14
RivistaChemCatChem
Volume4
Stato di pubblicazionePublished - 2012

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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