Heterocyclic rearrangements in constrained media. A zeolite-directed photorearrangement of 1,2,4-oxadiazoles

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Abstract

The first intrazeolite-photoinduced rearrangement of a five-membered heterocycle is reported. A completely different behavior compared to solution irradiations has been observed. The zeolite's role in directing the photoreaction of 3-phenyl-1,2,4-oxadiazoles toward the formation of the corresponding 1,3,4-oxadiazoles in a ring contraction−ring expansion route is discussed.
Lingua originaleEnglish
pagine (da-a)2322-2324
Numero di pagine3
RivistaJournal of Organic Chemistry
Volume70
Stato di pubblicazionePublished - 2005

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

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