A new variation on the Boulton-Katritzky reaction is reported, namely, involving use of a CNC side chain. A novel Montmorillonite-K10catalyzed nonreductive transamination of a 3-benzoyl-1,2,4-oxadiazole afforded a 3-(r-aminobenzyl)-1,2,4-oxadiazole, which was condensedwith benzaldehydes to afford the corresponding imines. In the presence of strong base, these imines underwent Boulton-Katritzky-typerearrangement to afford novel 4(5)-acylaminoimidazoles.
|Numero di pagine||3|
|Stato di pubblicazione||Published - 2010|
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