Electrochemical synthesis of coenzymes Qn by oxidation of tetramethoxy precursors

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Abstract

The electrochemical oxidation of tetramethoxy precursors (2) to coenzymes Q (n) (1) at a carbon anode was investigated both in a bench-scale batch electrochemical reactor and in a continuous recirculation reaction system equipped with a parallel-plate electrochemical divided cell. High faradic efficiency (> 60%) and excellent selectivity (> 90%) in coenzymes Q (n) were obtained in CH3CN or CH3CN/CH2Cl2 + 0.15 M Bu4NBF4 under potentiostatic or amperostatic alimentation.
Lingua originaleEnglish
pagine (da-a)2529-2533
Numero di pagine5
RivistaJournal of Applied Electrochemistry
Volume39
Stato di pubblicazionePublished - 2009

All Science Journal Classification (ASJC) codes

  • ???subjectarea.asjc.1500.1500???
  • Electrochemistry
  • Materials Chemistry

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