Electrochemical oxidation of tetramethoxy precursor as a key step for the synthesis of coenzyme Q10

Giuseppe Filardo; Alessandro Galia; Onofrio Scialdone; Maria Antonietta Sabatino; M A Sabatino;   Galia A;   G Filardo;   O Scialdone

Electrochemical oxidation of tetramethoxy precursor as a key step for the synthesis of coenzyme Q10

Giuseppe Filardo, Alessandro Galia, Onofrio Scialdone, Maria Antonietta Sabatino, M A Sabatino; Galia A; G Filardo; O Scialdone

Risultato della ricerca: Article › peer review

4 Citazioni (Scopus)

Abstract

The feasibility of electrosynthesis of coenzyme Q10 (1) by electrooxidation of tetramethoxy precursor (2) has been investigated at carbon, Pt and BDD anodes in a divided cell. The process strongly depends on the applied potential, anode material and water content of the solvent. At carbon anodes in CH3CN/CH2Cl2 + 0.15 M Bu4NBF4 at proper operative conditions high faradic efficiency (>60%) and excellent selectivity (95-97%) of the target product were obtained

Lingua originale	Undefined/Unknown
pagine (da-a)	1355-1358
Rivista	Electrochemistry Communications
Volume	9
Stato di pubblicazione	Published - 2007

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title = "Electrochemical oxidation of tetramethoxy precursor as a key step for the synthesis of coenzyme Q10",

abstract = "The feasibility of electrosynthesis of coenzyme Q10 (1) by electrooxidation of tetramethoxy precursor (2) has been investigated at carbon, Pt and BDD anodes in a divided cell. The process strongly depends on the applied potential, anode material and water content of the solvent. At carbon anodes in CH3CN/CH2Cl2 + 0.15 M Bu4NBF4 at proper operative conditions high faradic efficiency (>60%) and excellent selectivity (95-97%) of the target product were obtained",

author = "Giuseppe Filardo and Alessandro Galia and Onofrio Scialdone and Sabatino, {Maria Antonietta} and {M A Sabatino; Galia A; G Filardo; O Scialdone}",

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pages = "1355--1358",

journal = "Electrochemistry Communications",

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T1 - Electrochemical oxidation of tetramethoxy precursor as a key step for the synthesis of coenzyme Q10

AU - Filardo, Giuseppe

AU - Galia, Alessandro

AU - Scialdone, Onofrio

AU - Sabatino, Maria Antonietta

AU - M A Sabatino; Galia A; G Filardo; O Scialdone

PY - 2007

Y1 - 2007

N2 - The feasibility of electrosynthesis of coenzyme Q10 (1) by electrooxidation of tetramethoxy precursor (2) has been investigated at carbon, Pt and BDD anodes in a divided cell. The process strongly depends on the applied potential, anode material and water content of the solvent. At carbon anodes in CH3CN/CH2Cl2 + 0.15 M Bu4NBF4 at proper operative conditions high faradic efficiency (>60%) and excellent selectivity (95-97%) of the target product were obtained

AB - The feasibility of electrosynthesis of coenzyme Q10 (1) by electrooxidation of tetramethoxy precursor (2) has been investigated at carbon, Pt and BDD anodes in a divided cell. The process strongly depends on the applied potential, anode material and water content of the solvent. At carbon anodes in CH3CN/CH2Cl2 + 0.15 M Bu4NBF4 at proper operative conditions high faradic efficiency (>60%) and excellent selectivity (95-97%) of the target product were obtained

UR - http://hdl.handle.net/10447/14879

M3 - Article

SN - 1388-2481

VL - 9

SP - 1355

EP - 1358

JO - Electrochemistry Communications

JF - Electrochemistry Communications

ER -