Distribution of REEs in box-core sediments offshore an industrial area in SESicily, Ionian Sea: Evidence of anomalous sedimentary inputs

Adriana Bellanca, Rossella Di Leonardo, Rodolfo Neri, Giorgio Tranchida, Salvo Mazzola

Risultato della ricerca: Article

26 Citazioni (Scopus)

Abstract

The distribution of rare earth elements and yttrium (REEs + Y) has been investigated in box-core sediments recovered from four stations in the Sicilian coastal zone seawards of Augusta, one of the most industrialized and contaminated areas in the Mediterranean region. Shale-like REE patterns and low Y/Ho ratios (close to the chondritic ratio) suggest a dominant terrigenous (geogenic) source for REE. Slightenrichment of LREE over the HREE is interpreted as due to preferential adsorptive transfer of LREE from seawater to sediment particles. Samples from offshore cores exhibit slightly positive Gd and negative Ce anomalies. It is here hypothesized that main drivers of anthropogenic Gd flux towards the offshore are dredged contaminated materials that, recovered from the Augusta Bay, have been repeatedly discharged offshore. Consistent with the redox-chemistry of Ce, these anomalous sedimentary inputs induce a decrease of O2 concentration in the sediment, which in turn triggers Ce regeneration.
Lingua originaleEnglish
pagine (da-a)778-784
Numero di pagine7
RivistaChemosphere
Volume77
Stato di pubblicazionePublished - 2009

All Science Journal Classification (ASJC) codes

  • Environmental Engineering
  • Environmental Chemistry
  • Chemistry(all)
  • Pollution
  • Health, Toxicology and Mutagenesis

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