Designing fluorous domains. Synthesis of a series of pyridinium salts bearing a perfluoroalkylated azole moiety

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Abstract

The synthesis of a series of N-methylpyridinium salts bearing a perfluoroalkylated 1,2,4-oxadiazole or 1,2,4-triazole moiety is reported. X-Ray structures of representative perfluoroalkyl-triazolylpyridine (15) and methylpyridinium iodide salt (5a) are reported. Their crystal packing clearly shows segregation between the aromatic and parallel double layer fluorinated regions.
Lingua originaleEnglish
pagine (da-a)307-321
Numero di pagine15
RivistaHeterocycles
Volume68
Stato di pubblicazionePublished - 2006

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry
  • Pharmacology
  • Organic Chemistry

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