Abstract
| Lingua originale | English |
|---|---|
| pagine (da-a) | 3-8 |
| Numero di pagine | 6 |
| Rivista | Journal of Molecular Structure |
| Volume | 769 |
| Stato di pubblicazione | Published - 2006 |
All Science Journal Classification (ASJC) codes
- Biochemistry
- Physical and Theoretical Chemistry
- Condensed Matter Physics
Cita questo
Competition between inter- and intra-molecular energy exchanges in a simple quantum model of a dimer. / Napoli, Anna; Cusati; Napoli; Messina.
In: Journal of Molecular Structure, Vol. 769, 2006, pag. 3-8.Risultato della ricerca: Article
}
TY - JOUR
T1 - Competition between inter- and intra-molecular energy exchanges in a simple quantum model of a dimer
AU - Napoli, Anna
AU - Cusati, null
AU - Napoli, null
AU - Messina, null
PY - 2006
Y1 - 2006
N2 - We propose a fully quantum model to describe the dynamics of a possible radiationless energy transfer process between identical and nearly localized molecules or monomers coupled through a dipole–dipole term. The system is studied as an environmentally isolated dimeric pair and we find that its dynamics exhibits a competition between the process ruling out the transfer of energy among different degrees of freedom of a given monomer and the one steering the intermolecular passage of excitations from a monomer to the other one. Such a competition is quantitatively characterized investigating on the temporal behaviour of quantum covariances of some couples of appropriate observables having a clear physical meaning
AB - We propose a fully quantum model to describe the dynamics of a possible radiationless energy transfer process between identical and nearly localized molecules or monomers coupled through a dipole–dipole term. The system is studied as an environmentally isolated dimeric pair and we find that its dynamics exhibits a competition between the process ruling out the transfer of energy among different degrees of freedom of a given monomer and the one steering the intermolecular passage of excitations from a monomer to the other one. Such a competition is quantitatively characterized investigating on the temporal behaviour of quantum covariances of some couples of appropriate observables having a clear physical meaning
UR - http://hdl.handle.net/10447/13532
M3 - Article
VL - 769
SP - 3
EP - 8
JO - Journal of Molecular Structure
JF - Journal of Molecular Structure
SN - 0022-2860
ER -