Catalytic Synergism in a C60IL10TEMPO2 Hybrid in the Efficient Oxidation of Alcohols

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29 Citazioni (Scopus)

Abstract

A novel fullerene [5:1]hexakisadductbearing two 2,2,6,6-tetramethylpiperidine 1-oxyl (TEMPO) radicals and ten 1-propyl-3-ethylimidazolium bromide moieties has been synthesized and characterized. Such an C60IL10TEMPO2 hybrid has been successfully employed as a catalyst in the selective oxidation of a wide series of alcohols and is highly active at just 0.1 mol% loading. Moreover, it can be easily recovered by adsorption onto a multilayered covalently-linked SILP phase (mlc-SILP) through a “release and catch” approach and reused for up to 12 cycles without loss in efficiency. Interestingly, a catalytic synergistic effect of TEMPO and imidazolium bromide moieties combined in the same hybrid has been clearly shown.
Lingua originaleEnglish
pagine (da-a)51-58
Numero di pagine8
RivistaADVANCED SYNTHESIS & CATALYSIS
Volume357
Stato di pubblicazionePublished - 2015

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Organic Chemistry

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