Breakthrough in the alfa-perchlorination of acyl chlorides

Francesca D'Anna; Vincenzo Frenna; Federico Reverberi; Fulvia Felluga; Franco Bellesia; Franco Ghelfi; Domenico Spinelli; Andrew F. Parsons

Breakthrough in the alfa-perchlorination of acyl chlorides

Francesca D'Anna, Vincenzo Frenna, Federico Reverberi, Fulvia Felluga, Franco Bellesia, Franco Ghelfi, Domenico Spinelli, Andrew F. Parsons

Scienze e Tecnologie Biologiche Chimiche e Farmaceutiche

Risultato della ricerca: Article › peer review

7 Citazioni (Scopus)

Abstract

The preparation of -perchloroacyl chlorides, from reaction of the corresponding unfunctionalized acyl halides with chlorine, was efficiently achieved under base-catalysis, using a tetraalkylammonium chloride as catalyst. The process is solvent-free and the procedure is easy, inexpensive, and suitable for scale-up.

Lingua originale	English
pagine (da-a)	605-609
Numero di pagine	5
Rivista	Synthesis
Volume	44
Stato di pubblicazione	Published - 2012

All Science Journal Classification (ASJC) codes

Catalysis
Organic Chemistry

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title = "Breakthrough in the alfa-perchlorination of acyl chlorides",

abstract = "The preparation of -perchloroacyl chlorides, from reaction of the corresponding unfunctionalized acyl halides with chlorine, was efficiently achieved under base-catalysis, using a tetraalkylammonium chloride as catalyst. The process is solvent-free and the procedure is easy, inexpensive, and suitable for scale-up.",

keywords = "acyl chlorides, base catalysis, chlorine, halogenation, acyl chlorides, base catalysis, chlorine, halogenation",

author = "Francesca D'Anna and Vincenzo Frenna and Federico Reverberi and Fulvia Felluga and Franco Bellesia and Franco Ghelfi and Domenico Spinelli and Parsons, {Andrew F.}",

year = "2012",

language = "English",

volume = "44",

pages = "605--609",

journal = "Synthesis",

issn = "0039-7881",

publisher = "Georg Thieme Verlag",

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TY - JOUR

T1 - Breakthrough in the alfa-perchlorination of acyl chlorides

AU - D'Anna, Francesca

AU - Frenna, Vincenzo

AU - Reverberi, Federico

AU - Felluga, Fulvia

AU - Bellesia, Franco

AU - Ghelfi, Franco

AU - Spinelli, Domenico

AU - Parsons, Andrew F.

PY - 2012

Y1 - 2012

N2 - The preparation of -perchloroacyl chlorides, from reaction of the corresponding unfunctionalized acyl halides with chlorine, was efficiently achieved under base-catalysis, using a tetraalkylammonium chloride as catalyst. The process is solvent-free and the procedure is easy, inexpensive, and suitable for scale-up.

AB - The preparation of -perchloroacyl chlorides, from reaction of the corresponding unfunctionalized acyl halides with chlorine, was efficiently achieved under base-catalysis, using a tetraalkylammonium chloride as catalyst. The process is solvent-free and the procedure is easy, inexpensive, and suitable for scale-up.

KW - acyl chlorides

KW - base catalysis

KW - chlorine

KW - halogenation

KW - acyl chlorides

KW - base catalysis

KW - chlorine

KW - halogenation

UR - http://hdl.handle.net/10447/62417

M3 - Article

VL - 44

SP - 605

EP - 609

JO - Synthesis

JF - Synthesis

SN - 0039-7881

ER -