TY - JOUR
T1 - Assembly of Modular Asymmetric Organic-Inorganic Polyoxometalate Hybrids into Anisotropic Nanostructures
AU - Pignataro, Bruno Giuseppe
AU - Mathieson, Jennifer S.
AU - Song, Yu-Fei
AU - Musumeci, Chiara
AU - Rosnes, Mali H.
AU - Pradeep, Chullikkattil P.
AU - Cronin, Leroy
AU - Cogdell, Richard
AU - Long, De-Liang
PY - 2010
Y1 - 2010
N2 - Three organic-inorganic hybrid Mn-Anderson polyoxometalates (POMs), with both symmetrical and asymmetrical appended groups, have been synthesized, identified using electrospray mass spectrometry, and isolated using an approach that allows the three AA, BB, and AB compounds to be structurally characterized. Investigation of the self-assembly of the hybridson hydrophilic surfaces reveals the formation of nanofibres with characteristics that reflect the nature of the substitution of the POM yielding a route to the programmed assembly of anisotropic hybrid nanostructures.
AB - Three organic-inorganic hybrid Mn-Anderson polyoxometalates (POMs), with both symmetrical and asymmetrical appended groups, have been synthesized, identified using electrospray mass spectrometry, and isolated using an approach that allows the three AA, BB, and AB compounds to be structurally characterized. Investigation of the self-assembly of the hybridson hydrophilic surfaces reveals the formation of nanofibres with characteristics that reflect the nature of the substitution of the POM yielding a route to the programmed assembly of anisotropic hybrid nanostructures.
KW - Hybrid Anysotropic Nanostructures
KW - Langmuir-Blodgett
KW - Polyoxomethalates
KW - Scanning Force Microscopy
KW - Self-assembly
KW - Hybrid Anysotropic Nanostructures
KW - Langmuir-Blodgett
KW - Polyoxomethalates
KW - Scanning Force Microscopy
KW - Self-assembly
UR - http://hdl.handle.net/10447/51660
M3 - Article
VL - 132
SP - 15490
EP - 15492
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
ER -