A Simple Procedure for Oxidation of Alcohols using [Bis(acetoxy)iodo]benzene and a Catalytic Amount of Bromide Ions in Ethyl Acetate

Michelangelo Gruttadauria; Anna Maria Pia Salvo; Francesco Giacalone; Hazi  Ahmad Beejapur; Vincenzo Campisciano

A Simple Procedure for Oxidation of Alcohols using [Bis(acetoxy)iodo]benzene and a Catalytic Amount of Bromide Ions in Ethyl Acetate

Michelangelo Gruttadauria, Anna Maria Pia Salvo, Francesco Giacalone, Hazi Ahmad Beejapur, Vincenzo Campisciano

Risultato della ricerca: Article

Abstract

primary and secondary benzylic alcohols and secondary aliphatic alcohols were oxidized to the corresponding aldehydes and ketones using [bis(acetoxy)iodo]benzene (BAIB) and a catalytic amount of bromide ions, from tetrabutylammonium bromide or KBr, in ethyl acetate. The catalytic role of bromide ions was also highlighted in the oxidation of primary aliphatic alcohols and secondary allylic alcohols carried out in the presence of 1 mol% of TEMPO.

Lingua originale	English
pagine (da-a)	1179-1184
Numero di pagine	6
Rivista	Synlett
Stato di pubblicazione	Published - 2015

All Science Journal Classification (ASJC) codes

Organic Chemistry

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Cita questo

Gruttadauria, M., Salvo, A. M. P., Giacalone, F., Beejapur, H. A., & Campisciano, V. (2015). A Simple Procedure for Oxidation of Alcohols using [Bis(acetoxy)iodo]benzene and a Catalytic Amount of Bromide Ions in Ethyl Acetate. Synlett, 1179-1184.

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abstract = "primary and secondary benzylic alcohols and secondary aliphatic alcohols were oxidized to the corresponding aldehydes and ketones using [bis(acetoxy)iodo]benzene (BAIB) and a catalytic amount of bromide ions, from tetrabutylammonium bromide or KBr, in ethyl acetate. The catalytic role of bromide ions was also highlighted in the oxidation of primary aliphatic alcohols and secondary allylic alcohols carried out in the presence of 1 mol% of TEMPO.",

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AU - Gruttadauria, Michelangelo

AU - Salvo, Anna Maria Pia

AU - Giacalone, Francesco

AU - Beejapur, Hazi Ahmad

AU - Campisciano, Vincenzo

PY - 2015

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AB - primary and secondary benzylic alcohols and secondary aliphatic alcohols were oxidized to the corresponding aldehydes and ketones using [bis(acetoxy)iodo]benzene (BAIB) and a catalytic amount of bromide ions, from tetrabutylammonium bromide or KBr, in ethyl acetate. The catalytic role of bromide ions was also highlighted in the oxidation of primary aliphatic alcohols and secondary allylic alcohols carried out in the presence of 1 mol% of TEMPO.

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UR - https://www.thieme-connect.com/products/ejournals/abstract/10.1055/s-0034-1380196?lang=en

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