A Simple Procedure for Oxidation of Alcohols using [Bis(acetoxy)iodo]benzene and a Catalytic Amount of Bromide Ions in Ethyl Acetate

Michelangelo Gruttadauria; Anna Maria Pia Salvo; Vincenzo Campisciano; Francesco Giacalone; Hazi  Ahmad Beejapur

A Simple Procedure for Oxidation of Alcohols using [Bis(acetoxy)iodo]benzene and a Catalytic Amount of Bromide Ions in Ethyl Acetate

Michelangelo Gruttadauria, Anna Maria Pia Salvo, Vincenzo Campisciano, Francesco Giacalone, Hazi Ahmad Beejapur

Risultato della ricerca: Article › peer review

Abstract

primary and secondary benzylic alcohols and secondary aliphatic alcohols were oxidized to the corresponding aldehydes and ketones using [bis(acetoxy)iodo]benzene (BAIB) and a catalytic amount of bromide ions, from tetrabutylammonium bromide or KBr, in ethyl acetate. The catalytic role of bromide ions was also highlighted in the oxidation of primary aliphatic alcohols and secondary allylic alcohols carried out in the presence of 1 mol% of TEMPO.

Lingua originale	English
pagine (da-a)	1179-1184
Numero di pagine	6
Rivista	Synlett
Stato di pubblicazione	Published - 2015

All Science Journal Classification (ASJC) codes

Organic Chemistry

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abstract = "primary and secondary benzylic alcohols and secondary aliphatic alcohols were oxidized to the corresponding aldehydes and ketones using [bis(acetoxy)iodo]benzene (BAIB) and a catalytic amount of bromide ions, from tetrabutylammonium bromide or KBr, in ethyl acetate. The catalytic role of bromide ions was also highlighted in the oxidation of primary aliphatic alcohols and secondary allylic alcohols carried out in the presence of 1 mol% of TEMPO.",

author = "Michelangelo Gruttadauria and Salvo, {Anna Maria Pia} and Vincenzo Campisciano and Francesco Giacalone and Beejapur, {Hazi Ahmad}",

year = "2015",

language = "English",

pages = "1179--1184",

journal = "Synlett",

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T1 - A Simple Procedure for Oxidation of Alcohols using [Bis(acetoxy)iodo]benzene and a Catalytic Amount of Bromide Ions in Ethyl Acetate

AU - Gruttadauria, Michelangelo

AU - Salvo, Anna Maria Pia

AU - Campisciano, Vincenzo

AU - Giacalone, Francesco

AU - Beejapur, Hazi Ahmad

PY - 2015

Y1 - 2015

N2 - primary and secondary benzylic alcohols and secondary aliphatic alcohols were oxidized to the corresponding aldehydes and ketones using [bis(acetoxy)iodo]benzene (BAIB) and a catalytic amount of bromide ions, from tetrabutylammonium bromide or KBr, in ethyl acetate. The catalytic role of bromide ions was also highlighted in the oxidation of primary aliphatic alcohols and secondary allylic alcohols carried out in the presence of 1 mol% of TEMPO.

AB - primary and secondary benzylic alcohols and secondary aliphatic alcohols were oxidized to the corresponding aldehydes and ketones using [bis(acetoxy)iodo]benzene (BAIB) and a catalytic amount of bromide ions, from tetrabutylammonium bromide or KBr, in ethyl acetate. The catalytic role of bromide ions was also highlighted in the oxidation of primary aliphatic alcohols and secondary allylic alcohols carried out in the presence of 1 mol% of TEMPO.

UR - http://hdl.handle.net/10447/132232

UR - https://www.thieme-connect.com/products/ejournals/abstract/10.1055/s-0034-1380196?lang=en

M3 - Article

SP - 1179

EP - 1184

JO - Synlett

JF - Synlett

SN - 0936-5214

ER -