TY - JOUR
T1 - A Simple Procedure for Oxidation of Alcohols using [Bis(acetoxy)iodo]benzene and a Catalytic Amount of Bromide Ions in Ethyl Acetate
AU - Gruttadauria, Michelangelo
AU - Salvo, Anna Maria Pia
AU - Campisciano, Vincenzo
AU - Giacalone, Francesco
AU - Beejapur, Hazi Ahmad
PY - 2015
Y1 - 2015
N2 - primary and secondary benzylic alcohols and secondary aliphatic alcohols were oxidized to the corresponding aldehydes and ketones using [bis(acetoxy)iodo]benzene (BAIB) and a catalytic amount of bromide ions, from tetrabutylammonium bromide or KBr, in ethyl acetate. The catalytic role of bromide ions was also highlighted in the oxidation of primary aliphatic alcohols and secondary allylic alcohols carried out in the presence of 1 mol% of TEMPO.
AB - primary and secondary benzylic alcohols and secondary aliphatic alcohols were oxidized to the corresponding aldehydes and ketones using [bis(acetoxy)iodo]benzene (BAIB) and a catalytic amount of bromide ions, from tetrabutylammonium bromide or KBr, in ethyl acetate. The catalytic role of bromide ions was also highlighted in the oxidation of primary aliphatic alcohols and secondary allylic alcohols carried out in the presence of 1 mol% of TEMPO.
UR - http://hdl.handle.net/10447/132232
UR - https://www.thieme-connect.com/products/ejournals/abstract/10.1055/s-0034-1380196?lang=en
M3 - Article
SP - 1179
EP - 1184
JO - Synlett
JF - Synlett
SN - 0936-5214
ER -