A new palladium(II)-catalyzed [3,3] aza-Claisen rearrangementof 3-allyloxy-5-aryl-1,2,4-oxadiazoles

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Abstract

A new efficient palladium(II)-catalyzed [3,3] aza-Claisen, formal sigmatropic rearrangement of 3-allyloxy-5-aryl-1,2,4-oxadiazoles was developed. The mechanism was studied by analyzing the regiochemicaland stereochemical course of the reaction. The results obtained indicated the intervention of a cationicpallada-cycle similar to the one postulated for the Cope rearrangement of 1,5-dienes.
Lingua originaleEnglish
pagine (da-a)884-886
Numero di pagine3
RivistaTetrahedron Letters
VolumeTetrahedron Letters 52 (2011) 884–886
Stato di pubblicazionePublished - 2011

All Science Journal Classification (ASJC) codes

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  • ???subjectarea.asjc.3000.3002???
  • ???subjectarea.asjc.1600.1605???

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