Abstract
A new efficient palladium(II)-catalyzed [3,3] aza-Claisen, formal sigmatropic rearrangement of 3-allyloxy-5-aryl-1,2,4-oxadiazoles was developed. The mechanism was studied by analyzing the regiochemicaland stereochemical course of the reaction. The results obtained indicated the intervention of a cationicpallada-cycle similar to the one postulated for the Cope rearrangement of 1,5-dienes.
| Lingua originale | English |
|---|---|
| pagine (da-a) | 884-886 |
| Numero di pagine | 3 |
| Rivista | Tetrahedron Letters |
| Volume | Tetrahedron Letters 52 (2011) 884–886 |
| Stato di pubblicazione | Published - 2011 |
All Science Journal Classification (ASJC) codes
- ???subjectarea.asjc.1300.1303???
- ???subjectarea.asjc.3000.3002???
- ???subjectarea.asjc.1600.1605???