A magnetic self-contained thermochromic system with convenient temperature range

Francesca D'Anna; Floriana Billeci; Natalia V. Plechkova; H. Q. Nimal Gunaratne; Kenneth R. Seddon; Floriana Billeci; Grace G. Morgan

A magnetic self-contained thermochromic system with convenient temperature range

Francesca D'Anna, Floriana Billeci, Natalia V. Plechkova, H. Q. Nimal Gunaratne, Kenneth R. Seddon, Floriana Billeci, Grace G. Morgan

Risultato della ricerca: Article › peer review

13 Citazioni (Scopus)

Abstract

A new ionic liquid with sugar-based ligand has been prepared andused to coordinate cobalt(II), at low loading, in an ionic liquid solution.The system obtained reveals magnetic switching and markedthermochromism in solution/polymer films over a convenienttemperature range (20–60 °C). This system is self-contained,devoid of any volatile substances, and reproducible over multiplethermal cycles. The colour change can be attributed to a change inthe coordination geometry from octahedral (pink) at room temperatureto tetrahedral (blue) on warming, monitored by 59Co NMRspectroscopy, which was used for the first time to study thechange. This material may find applications in stimuli-responsivesmart systems aimed at energy storage applications.

Lingua originale	English
pagine (da-a)	1412-1416
Numero di pagine	5
Rivista	Green Chemistry
Volume	21
Stato di pubblicazione	Published - 2019

All Science Journal Classification (ASJC) codes

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@article{6935733aa4b3429284b69cfcfbd00fc3,

title = "A magnetic self-contained thermochromic system with convenient temperature range",

abstract = "A new ionic liquid with sugar-based ligand has been prepared andused to coordinate cobalt(II), at low loading, in an ionic liquid solution.The system obtained reveals magnetic switching and markedthermochromism in solution/polymer films over a convenienttemperature range (20–60 °C). This system is self-contained,devoid of any volatile substances, and reproducible over multiplethermal cycles. The colour change can be attributed to a change inthe coordination geometry from octahedral (pink) at room temperatureto tetrahedral (blue) on warming, monitored by 59Co NMRspectroscopy, which was used for the first time to study thechange. This material may find applications in stimuli-responsivesmart systems aimed at energy storage applications.",

author = "Francesca D'Anna and Floriana Billeci and Plechkova, {Natalia V.} and Gunaratne, {H. Q. Nimal} and Seddon, {Kenneth R.} and Floriana Billeci and Morgan, {Grace G.}",

year = "2019",

language = "English",

volume = "21",

pages = "1412--1416",

journal = "Green Chemistry",

issn = "1463-9262",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - A magnetic self-contained thermochromic system with convenient temperature range

AU - D'Anna, Francesca

AU - Billeci, Floriana

AU - Plechkova, Natalia V.

AU - Gunaratne, H. Q. Nimal

AU - Seddon, Kenneth R.

AU - Billeci, Floriana

AU - Morgan, Grace G.

PY - 2019

Y1 - 2019

N2 - A new ionic liquid with sugar-based ligand has been prepared andused to coordinate cobalt(II), at low loading, in an ionic liquid solution.The system obtained reveals magnetic switching and markedthermochromism in solution/polymer films over a convenienttemperature range (20–60 °C). This system is self-contained,devoid of any volatile substances, and reproducible over multiplethermal cycles. The colour change can be attributed to a change inthe coordination geometry from octahedral (pink) at room temperatureto tetrahedral (blue) on warming, monitored by 59Co NMRspectroscopy, which was used for the first time to study thechange. This material may find applications in stimuli-responsivesmart systems aimed at energy storage applications.

AB - A new ionic liquid with sugar-based ligand has been prepared andused to coordinate cobalt(II), at low loading, in an ionic liquid solution.The system obtained reveals magnetic switching and markedthermochromism in solution/polymer films over a convenienttemperature range (20–60 °C). This system is self-contained,devoid of any volatile substances, and reproducible over multiplethermal cycles. The colour change can be attributed to a change inthe coordination geometry from octahedral (pink) at room temperatureto tetrahedral (blue) on warming, monitored by 59Co NMRspectroscopy, which was used for the first time to study thechange. This material may find applications in stimuli-responsivesmart systems aimed at energy storage applications.

UR - http://hdl.handle.net/10447/349100

M3 - Article

SN - 1463-9262

VL - 21

SP - 1412

EP - 1416

JO - Green Chemistry

JF - Green Chemistry

ER -

A magnetic self-contained thermochromic system with convenient temperature range

Abstract

All Science Journal Classification (ASJC) codes

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