Structure of D-ribonic acid-dimethyltin(IV) in coordinating solvents: an experimental and DFT 119Sn NMR study.

Girolamo Casella, Lorenzo Pellerito, Giacomo Saielli, Alessandro Bagno, Ivan Diego Sciacca, Nuccio Bertazzi

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8 Citations (Scopus)

Abstract

We have investigated a newly synthesized complex of D-ribonic acid with dimethyltin(IV). The structure of the complex in solution has been characterized by means of 1H, 13C, and 119Sn NMR and by DFT calculations. The comparison of experimental and computational results allowed the determination of the stable conformation in solution as well as the detection of a dimerization process. Moreover, evidence is given of active coordination of the metal by the solvent.
Original languageEnglish
Pages (from-to)874-883
Number of pages10
JournalJournal of Physical Organic Chemistry
Volume19
Publication statusPublished - 2006

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry

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