MORPHOLOGY OF 1-ALKYL-3-METHYLIMIDAZOLIUM HEXAFLUOROPHOSPHATE ROOM TEMPERATURE IONIC LIQUIDS

Roberto Triolo, Alessandro Triolo

    Research output: Contribution to journalArticlepeer-review

    Abstract

    The structural organization in selected room temperature ionic liquids, namely (a) butyl-, (b) hexyl- and (c) octyl-3-methylimidazolium hexafluorophosphate, is investigated by means of X-ray diffraction. We find novel experimental evidences of the existence of a high degree of intermediate range order that is associated to nanoscale segregation of the alkyl chains into the charged matrix. The size of these structural heterogeneities depends linearly from the alkyl chain length. A similar behaviour had been observed in other systems, such as normal alcohols. The slope of such dependence provides hints on the nature of the structural organization of these segregated domains.
    Original languageEnglish
    Pages (from-to)362-365
    JournalChemical Physics Letters
    Volume457
    Publication statusPublished - 2008

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