Efficient Conversion of Carbon Dioxide by Imidazolium-Based Cross-Linked Nanostructures Containing Polyhedral Oligomeric Silsesquioxane (POSS) Building Blocks

Carla Calabrese, Vincenzo Campisciano, Francesco Giacalone, Michelangelo Gruttadauria, Luca Fusaro, Adrien Comès, Carla Calabrese, Leonarda Francesca Liotta, Carmela Aprile, Carmela Aprile, Leonarda Francesca Liotta

Research output: Contribution to journalArticle

Abstract

Polyhedral oligomeric silsesquioxanes (POSS) have been employed as molecular building blocks for the synthesis of imidazolium cross-linked networks, to be used as heterogeneous catalysts for the conversion of carbon dioxide into cyclic carbonates. Two hybrid materials with different nucleophilic species (bromide and iodide) have been prepared and characterized by means of elemental analysis, 13C and 29Si solid-state NMR spectroscopy, thermogravimetric analysis and IR spectroscopy. The solids were tested as the sole catalyst under metal- and solvent-free reaction conditions showing full selectivity toward the formation of cyclic carbonates. High turnover number (TON) and productivity values, up to 5502 and 1081 respectively for glycidol conversion at 100 °C and up to 4942 and 1122 for epichlorohydrin conversion at 150 °C after 3 h, were obtained. Such outstanding productivity values were ascribed to the optimal organic/inorganic (i. e., imidazolium moiety/POSS support) weight ratio. The recyclability of the materials was successfully verified for five consecutive runs allowing their consideration as promising candidates for continuous flow technologies.
Original languageEnglish
Pages (from-to)1536-1543
Number of pages8
JournalChemPlusChem
Volume84
Publication statusPublished - 2019

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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