Effect of Hydration Procedure of Fumed Silica Precursor on the Formation of Luminescent Carbon Centers in SiO2:C Nanocomposites

Marco Cannas, Lavinia Vaccaro, Volodymyr Lysenko, Volodymyr Lysenko, Alexei Nazarov, Dmytro Kysil, Stanislav Sevostianov, Oksana Isaieva, Dmytro Virnyi, Volodymyr Lysenko, Yuri P. Piryatinski, Galyna Rudko, Valentyn Tertykh, Andrii Vasin

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Abstract

The effect of hydration procedure of fumed silica precursor on photoluminescent properties of carbonized silica (SiO2:C) nanocomposite after chemo/thermal treatments is studied. Main structural effect is the formation of chemical bonding of phenyl groups to silica surface via multiple CSiO bonding bridges. Synthesized samples demonstrate very broad photoluminescence (PL) bands in near ultraviolet and visible ranges with maximum intensity dependent on temperature of thermal annealing. Two main trends in luminescence properties are: 1) hydration-induced blue shift of PL in comparison with PL of unhydrated series; 2) red shift of PL bands with increasing synthesis temperature regardless hydration procedure. Temperature dependent evolution of light emission bands is discussed in terms of surface carbon nanoclusters formation and aggregation processes. It is assumed that blue shift of PL bands in the hydrated series is associated with the decreased surface mobility of carbon atoms and clusters as a result of increased chemical bonding with silica surface that slows down carbon thermally stimulated clusterization/aggregation processes.
Original languageEnglish
Pages (from-to)1800560-1-1800560-8
Number of pages8
JournalPHYSICA STATUS SOLIDI. A, APPLICATIONS AND MATERIALS SCIENCE
Volume216
Publication statusPublished - 2019

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Electrical and Electronic Engineering
  • Materials Chemistry

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  • Cite this

    Cannas, M., Vaccaro, L., Lysenko, V., Lysenko, V., Nazarov, A., Kysil, D., Sevostianov, S., Isaieva, O., Virnyi, D., Lysenko, V., Piryatinski, Y. P., Rudko, G., Tertykh, V., & Vasin, A. (2019). Effect of Hydration Procedure of Fumed Silica Precursor on the Formation of Luminescent Carbon Centers in SiO2:C Nanocomposites. PHYSICA STATUS SOLIDI. A, APPLICATIONS AND MATERIALS SCIENCE, 216, 1800560-1-1800560-8.